The shared side and the empty overlap
The word adjacent in this topic really means side-by-side. If one angle lies on top of part of the other, the pair may share a ray and a vertex, but they are not adjacent in the formal geometric sense.
Adjacent angles show up constantly in polygons, line intersections, and angle addition. Reading them correctly helps students decide when a larger angle is being built from two smaller parts.
Picture two doors opening from the same hinge, one beside the other. The hinge is like the shared vertex, and the edge between the doors is like the common side. If the two openings cover the same space, they are not adjacent, even if they share a point.
Adjacency describes position, not a total measure. Two adjacent angles might add to 90 degrees, 180 degrees, or another number. First decide whether they are next to each other; only then look for a special relationship such as complementary or supplementary.